[Mn(MAC){mu(1,5)-N(CN)(2)}](PF6): a new one-dimensional coordination polymer with mu(1,5)-dicyanamido bridges (MAC = pentaaza macrocyclic ligand) - synthesis, crystal structure and magnetic properties

Paraschiv C, Sutter JP, Schmidtmann M, Müller A, Andruh M (2003)
POLYHEDRON 22(12): 1611-1615.

Journal Article | Published | English

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Abstract
The dicyanamido-bridged manganese(II) compound, [Mn(MAC){mu(1,5)-N(CN)(2)}](PF6), (1), has been obtained by reacting [Mn(MAC)(H2O)(2)]Cl-2.4H(2)O with NaN(CN)(2) and NaPF6 in a 1: 1: 1 molar ratio (MAC = 2,13-dimethyl-3,6,9,12,18-pentaazabicyclo-[12.3.1]octadeca-1(18),2,12,14 ,16-pentaene). The structure consists of [Mn(MAC){mu(1,5)-N(CN)(2)}](n)(n+) infinite chains and uncoordinated PF6- ions. The manganese ions display a pentagonal-bipyramidal geometry, with the macrocyclic ligand forming the equatorial plane. The {Mn(MAC)} units are connected through mu(1,5)-dicyanamido bridges (both nitrile nitrogens coordinated). The cryomagnetic investigation of 1 reveals a very weak exchange interaction between the manganese(II) ions within the chain (J = -0.49 cm(-1)). (C) 2003 Elsevier Science Ltd. All rights reserved.
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Paraschiv C, Sutter JP, Schmidtmann M, Müller A, Andruh M. [Mn(MAC){mu(1,5)-N(CN)(2)}](PF6): a new one-dimensional coordination polymer with mu(1,5)-dicyanamido bridges (MAC = pentaaza macrocyclic ligand) - synthesis, crystal structure and magnetic properties. POLYHEDRON. 2003;22(12):1611-1615.
Paraschiv, C., Sutter, J. P., Schmidtmann, M., Müller, A., & Andruh, M. (2003). [Mn(MAC){mu(1,5)-N(CN)(2)}](PF6): a new one-dimensional coordination polymer with mu(1,5)-dicyanamido bridges (MAC = pentaaza macrocyclic ligand) - synthesis, crystal structure and magnetic properties. POLYHEDRON, 22(12), 1611-1615.
Paraschiv, C., Sutter, J. P., Schmidtmann, M., Müller, A., and Andruh, M. (2003). [Mn(MAC){mu(1,5)-N(CN)(2)}](PF6): a new one-dimensional coordination polymer with mu(1,5)-dicyanamido bridges (MAC = pentaaza macrocyclic ligand) - synthesis, crystal structure and magnetic properties. POLYHEDRON 22, 1611-1615.
Paraschiv, C., et al., 2003. [Mn(MAC){mu(1,5)-N(CN)(2)}](PF6): a new one-dimensional coordination polymer with mu(1,5)-dicyanamido bridges (MAC = pentaaza macrocyclic ligand) - synthesis, crystal structure and magnetic properties. POLYHEDRON, 22(12), p 1611-1615.
C. Paraschiv, et al., “[Mn(MAC){mu(1,5)-N(CN)(2)}](PF6): a new one-dimensional coordination polymer with mu(1,5)-dicyanamido bridges (MAC = pentaaza macrocyclic ligand) - synthesis, crystal structure and magnetic properties”, POLYHEDRON, vol. 22, 2003, pp. 1611-1615.
Paraschiv, C., Sutter, J.P., Schmidtmann, M., Müller, A., Andruh, M.: [Mn(MAC){mu(1,5)-N(CN)(2)}](PF6): a new one-dimensional coordination polymer with mu(1,5)-dicyanamido bridges (MAC = pentaaza macrocyclic ligand) - synthesis, crystal structure and magnetic properties. POLYHEDRON. 22, 1611-1615 (2003).
Paraschiv, C, Sutter, JP, Schmidtmann, Marc, Müller, Achim, and Andruh, Marius. “[Mn(MAC){mu(1,5)-N(CN)(2)}](PF6): a new one-dimensional coordination polymer with mu(1,5)-dicyanamido bridges (MAC = pentaaza macrocyclic ligand) - synthesis, crystal structure and magnetic properties”. POLYHEDRON 22.12 (2003): 1611-1615.
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