Hydride abstraction from 1,3,5-cycloheptatriene by gaseous carbenium ions, as studied by Fourier transform ion cyclotron resonance kinetics and deuterium labeling

Mormann M, Kuck D (2003)
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY 16(10): 746-752.

Journal Article | Published | English

No fulltext has been uploaded

Author
;
Abstract
The gas-phase interaction of protonated acetone and tert-butyl cations with 1,3,5-cycloheptatriene was studied by Fourier transform ion cyclotron resonance (Fr-ICR) mass spectrometry. In addition to proton transfer giving C7H9+ ions, hydride abstraction from cycloheptatriene giving C7H7+ ions was observed. Deuterium labeling 9 experiments combined with the determination of the reaction kinetics excluded the formation of C-7-H-7(+) ions by consecutive proton transfer and H-2 expulsion under these conditions. The kinetic isotope effect measured for the hydride transfer channel was found to be in the range 1.65 +/- 0.1, very close to that known to operate during hydride transfer from simple alkylbenzenes to t-C4H9+ ions. Copyright (C) 2003 John Wiley Sons, Ltd.
Publishing Year
ISSN
PUB-ID

Cite this

Mormann M, Kuck D. Hydride abstraction from 1,3,5-cycloheptatriene by gaseous carbenium ions, as studied by Fourier transform ion cyclotron resonance kinetics and deuterium labeling. JOURNAL OF PHYSICAL ORGANIC CHEMISTRY. 2003;16(10):746-752.
Mormann, M., & Kuck, D. (2003). Hydride abstraction from 1,3,5-cycloheptatriene by gaseous carbenium ions, as studied by Fourier transform ion cyclotron resonance kinetics and deuterium labeling. JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 16(10), 746-752.
Mormann, M., and Kuck, D. (2003). Hydride abstraction from 1,3,5-cycloheptatriene by gaseous carbenium ions, as studied by Fourier transform ion cyclotron resonance kinetics and deuterium labeling. JOURNAL OF PHYSICAL ORGANIC CHEMISTRY 16, 746-752.
Mormann, M., & Kuck, D., 2003. Hydride abstraction from 1,3,5-cycloheptatriene by gaseous carbenium ions, as studied by Fourier transform ion cyclotron resonance kinetics and deuterium labeling. JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 16(10), p 746-752.
M. Mormann and D. Kuck, “Hydride abstraction from 1,3,5-cycloheptatriene by gaseous carbenium ions, as studied by Fourier transform ion cyclotron resonance kinetics and deuterium labeling”, JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, vol. 16, 2003, pp. 746-752.
Mormann, M., Kuck, D.: Hydride abstraction from 1,3,5-cycloheptatriene by gaseous carbenium ions, as studied by Fourier transform ion cyclotron resonance kinetics and deuterium labeling. JOURNAL OF PHYSICAL ORGANIC CHEMISTRY. 16, 746-752 (2003).
Mormann, Michael, and Kuck, Dietmar. “Hydride abstraction from 1,3,5-cycloheptatriene by gaseous carbenium ions, as studied by Fourier transform ion cyclotron resonance kinetics and deuterium labeling”. JOURNAL OF PHYSICAL ORGANIC CHEMISTRY 16.10 (2003): 746-752.
This data publication is cited in the following publications:
This publication cites the following data publications:

Export

0 Marked Publications

Open Data PUB

Web of Science

View record in Web of Science®

Search this title in

Google Scholar