Self-assembly and crystal hetero-octametallic molecular box structure of a novel (Chelate complexes, Part 23)

Saalfrank RW, Bernt I, Hampel F, Scheurer A, Nakajima T, Huma SHZ, Heinemann FW, Schmidtmann M, Müller A (2003)
In: POLYHEDRON. 22. PERGAMON-ELSEVIER SCIENCE LTD: 2985-2989.

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Abstract
Reaction of hexadentate ligand m-xylene-bis-(iminodiethanol) H4L2 (4) with lithium hydride and either copper(II) acetate or copper(II) chloride resulted in the formation of two completely different products. Starting from copper(II) acetate the green bis-dimetallic cyclophane [Cu-4(H2L22)(OAc)(4)](.)2CH(2)Cl(2) (5) was formed. However, when 4 was allowed to react with copper(II) chloride, the novel hetero-octametallic molecular box {[Li-4(Cu4O)(L-2)(2)](H2O)(2)(EtOH)(2)}Cl-2 (6) was isolated. Deep violet 6 can be described as two metallacrown ether sub-units linked together by a central mu(4)-bridging O-2(-)-ion. The structures of all new compounds were determined unequivocally by single crystal X-ray analyses. (C) 2003 Elsevier Ltd. All rights reserved.
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Saalfrank RW, Bernt I, Hampel F, et al. Self-assembly and crystal hetero-octametallic molecular box structure of a novel (Chelate complexes, Part 23). In: POLYHEDRON. Vol 22. PERGAMON-ELSEVIER SCIENCE LTD; 2003: 2985-2989.
Saalfrank, R. W., Bernt, I., Hampel, F., Scheurer, A., Nakajima, T., Huma, S. H. Z., Heinemann, F. W., et al. (2003). Self-assembly and crystal hetero-octametallic molecular box structure of a novel (Chelate complexes, Part 23). POLYHEDRON, 22(22), 2985-2989.
Saalfrank, R. W., Bernt, I., Hampel, F., Scheurer, A., Nakajima, T., Huma, S. H. Z., Heinemann, F. W., Schmidtmann, M., and Müller, A. (2003). “Self-assembly and crystal hetero-octametallic molecular box structure of a novel (Chelate complexes, Part 23)” in POLYHEDRON, vol. 22, (PERGAMON-ELSEVIER SCIENCE LTD), 2985-2989.
Saalfrank, R.W., et al., 2003. Self-assembly and crystal hetero-octametallic molecular box structure of a novel (Chelate complexes, Part 23). In POLYHEDRON. no.22 PERGAMON-ELSEVIER SCIENCE LTD, pp. 2985-2989.
R.W. Saalfrank, et al., “Self-assembly and crystal hetero-octametallic molecular box structure of a novel (Chelate complexes, Part 23)”, POLYHEDRON, vol. 22, PERGAMON-ELSEVIER SCIENCE LTD, 2003, pp.2985-2989.
Saalfrank, R.W., Bernt, I., Hampel, F., Scheurer, A., Nakajima, T., Huma, S.H.Z., Heinemann, F.W., Schmidtmann, M., Müller, A.: Self-assembly and crystal hetero-octametallic molecular box structure of a novel (Chelate complexes, Part 23). POLYHEDRON. 22, p. 2985-2989. PERGAMON-ELSEVIER SCIENCE LTD (2003).
Saalfrank, R. W., Bernt, I, Hampel, F, Scheurer, A, Nakajima, T, Huma, S. H. Z., Heinemann, F. W., Schmidtmann, Marc, and Müller, Achim. “Self-assembly and crystal hetero-octametallic molecular box structure of a novel (Chelate complexes, Part 23)”. POLYHEDRON. PERGAMON-ELSEVIER SCIENCE LTD, 2003.Vol. 22. 2985-2989.
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