Binuclear coordination compounds as building-blocks in designing polynuclear complexes

Pascu M, Andruh M, Müller A, Schmidtmann M (2004)
POLYHEDRON 23(4): 673-678.

Journal Article | Published | English

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Abstract
The syntheses and crystal structures of two new polynuclear complexes are reported: infinity(1)[Cu2L1(acdca)] . CH3OH . 4H(2)O (1) and [(CuZnL2)(2)(bpete)(2)](ClO4)(4) . 4.5CH(3)OH (2) (H2L1 is the Schiff-base proligand resulted from the condensation reaction of 2,6-diformyl-4-methyl-phenol with 1,3-diamino-propane; H2L2 is a dissymmetric macrocyclic Robson proligand resulted from 2,6-diformyl-4-methyl-phenol, ethylenediamine and diethylenetriamine). The two compounds have been obtained by reacting binuclear [Cu-2] and [CuZn] complexes with the dianion of the of the acetylene-dicarboxylic acid (acdca(2-)), and, respectively, bis(4-pyridyl)ethylene, bpete. The structure of 1 consists of linear chains resulted by connecting the {Cu2L1} moieties through acdca(2-) linkers. The copper(II) ions within the chains exhibit an elongated octahedral geometry. Compound 2 contains cationic [Cu2Zn2] rectangles, with the copper(II) ions, as well as the zinc(II) ions, diagonally disposed. (C) 2003 Elsevier Ltd. All rights reserved.
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Pascu M, Andruh M, Müller A, Schmidtmann M. Binuclear coordination compounds as building-blocks in designing polynuclear complexes. POLYHEDRON. 2004;23(4):673-678.
Pascu, M., Andruh, M., Müller, A., & Schmidtmann, M. (2004). Binuclear coordination compounds as building-blocks in designing polynuclear complexes. POLYHEDRON, 23(4), 673-678.
Pascu, M., Andruh, M., Müller, A., and Schmidtmann, M. (2004). Binuclear coordination compounds as building-blocks in designing polynuclear complexes. POLYHEDRON 23, 673-678.
Pascu, M., et al., 2004. Binuclear coordination compounds as building-blocks in designing polynuclear complexes. POLYHEDRON, 23(4), p 673-678.
M. Pascu, et al., “Binuclear coordination compounds as building-blocks in designing polynuclear complexes”, POLYHEDRON, vol. 23, 2004, pp. 673-678.
Pascu, M., Andruh, M., Müller, A., Schmidtmann, M.: Binuclear coordination compounds as building-blocks in designing polynuclear complexes. POLYHEDRON. 23, 673-678 (2004).
Pascu, M, Andruh, Marius, Müller, Achim, and Schmidtmann, Marc. “Binuclear coordination compounds as building-blocks in designing polynuclear complexes”. POLYHEDRON 23.4 (2004): 673-678.
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