On the complex hedgehog-shaped cluster species containing 368 Mo atoms: simple preparation method, new spectral details and information about the unique formation

Müller A, Botar B, Das SK, Bögge H, Schmidtmann M, Merca A (2004)
Polyhedron 23(15): 2381-2385.

Journal Article | Published | English

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Abstract
The deep-blue compound Na-48[HxMo368O1032(H2O)(240)(SO4)(48)] (.) ca. 1000H(2)O equivalent to Na-48 1a (.) ca. 1000H(2)O (1) exhibiting an unusual nanosized hedgehog-type cluster anion, could now be obtained in good yield - allowing now several materials science studies - in the presence of a high concentration of an electrolyte destroying the hydration shell, in only two days. 1 was characterized by elemental analysis (including redox titrations to determine the (formal) number of Mo-nu centers), thermogravimetry and spectroscopic methods (IR, resonance Raman, Vis/NIR). Information about unusual aspects of the formation is reported together with additional spectroscopic details as well Lis a new crystal structure determination of the very complex system while confirming the earlier one. (C) 2004 Elsevier Ltd. All rights reserved.
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Müller A, Botar B, Das SK, Bögge H, Schmidtmann M, Merca A. On the complex hedgehog-shaped cluster species containing 368 Mo atoms: simple preparation method, new spectral details and information about the unique formation. Polyhedron. 2004;23(15):2381-2385.
Müller, A., Botar, B., Das, S. K., Bögge, H., Schmidtmann, M., & Merca, A. (2004). On the complex hedgehog-shaped cluster species containing 368 Mo atoms: simple preparation method, new spectral details and information about the unique formation. Polyhedron, 23(15), 2381-2385.
Müller, A., Botar, B., Das, S. K., Bögge, H., Schmidtmann, M., and Merca, A. (2004). On the complex hedgehog-shaped cluster species containing 368 Mo atoms: simple preparation method, new spectral details and information about the unique formation. Polyhedron 23, 2381-2385.
Müller, A., et al., 2004. On the complex hedgehog-shaped cluster species containing 368 Mo atoms: simple preparation method, new spectral details and information about the unique formation. Polyhedron, 23(15), p 2381-2385.
A. Müller, et al., “On the complex hedgehog-shaped cluster species containing 368 Mo atoms: simple preparation method, new spectral details and information about the unique formation”, Polyhedron, vol. 23, 2004, pp. 2381-2385.
Müller, A., Botar, B., Das, S.K., Bögge, H., Schmidtmann, M., Merca, A.: On the complex hedgehog-shaped cluster species containing 368 Mo atoms: simple preparation method, new spectral details and information about the unique formation. Polyhedron. 23, 2381-2385 (2004).
Müller, Achim, Botar, Bogdan, Das, Samar K., Bögge, Hartmut, Schmidtmann, Marc, and Merca, Alice. “On the complex hedgehog-shaped cluster species containing 368 Mo atoms: simple preparation method, new spectral details and information about the unique formation”. Polyhedron 23.15 (2004): 2381-2385.
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