Extended structures constructed from alkoxo-bridged binuclear complexes as nodes and bis(4-pyridyl) ethylene as a spacer

Marin G, Tudor V, Kravtsov VC, Schmidtmann M, Simonov YA, Müller A, Andruh M (2005)
CRYSTAL GROWTH & DESIGN 5(1): 279-282.

Journal Article | Published | English

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Abstract
Two new polynuclear complexes have been obtained by connecting alkoxo-bridged binuclear copper(II) complexes with bis(4-pyridyl)ethylene (bpe): [Cu-2(Hdea)(2)(bpe)]-(bpe)-(ClO4)(2) (1) and [Cu-2(mea)(2)(bpe)(2)](ClO4)(2) (2) (Hdea = mono-deprotonated diethanolamine and mea = deprotonated monoethanolamine). The structure of 1 consists of infinite chains that have resulted by connecting the bis(alkoxo)-bridged centrosymmetrical [Cu-2(dea)(2)](2+) nodes with bis(4-pyridyl)ethylene rods. The (CuCu)-Cu-... separations within the chain are 2.984 and 13.308 Angstrom. The noncoordinated bpe molecules bind the parallel coordination polymer chains through hydrogen bond interactions, resulting in infinite gridlike sheets. Compound 2 exhibits an interlocked 3-D structure, resulting from the inclined interpenetration of 2-D gridlike sheets. Each sheet is constructed from [Cu-2(mea)(2)] nodes, interconnected by bpe spacers. Every mesh of every sheet contains parts of two others passing through it. The distance between the alkoxo-bridged copper(II) ions within the nodes is 3.020 Angstrom, while the distances between the copper ions bridged by bpe ligands are 13.381 and 14.051 Angstrom.
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Marin G, Tudor V, Kravtsov VC, et al. Extended structures constructed from alkoxo-bridged binuclear complexes as nodes and bis(4-pyridyl) ethylene as a spacer. CRYSTAL GROWTH & DESIGN. 2005;5(1):279-282.
Marin, G., Tudor, V., Kravtsov, V. C., Schmidtmann, M., Simonov, Y. A., Müller, A., & Andruh, M. (2005). Extended structures constructed from alkoxo-bridged binuclear complexes as nodes and bis(4-pyridyl) ethylene as a spacer. CRYSTAL GROWTH & DESIGN, 5(1), 279-282.
Marin, G., Tudor, V., Kravtsov, V. C., Schmidtmann, M., Simonov, Y. A., Müller, A., and Andruh, M. (2005). Extended structures constructed from alkoxo-bridged binuclear complexes as nodes and bis(4-pyridyl) ethylene as a spacer. CRYSTAL GROWTH & DESIGN 5, 279-282.
Marin, G., et al., 2005. Extended structures constructed from alkoxo-bridged binuclear complexes as nodes and bis(4-pyridyl) ethylene as a spacer. CRYSTAL GROWTH & DESIGN, 5(1), p 279-282.
G. Marin, et al., “Extended structures constructed from alkoxo-bridged binuclear complexes as nodes and bis(4-pyridyl) ethylene as a spacer”, CRYSTAL GROWTH & DESIGN, vol. 5, 2005, pp. 279-282.
Marin, G., Tudor, V., Kravtsov, V.C., Schmidtmann, M., Simonov, Y.A., Müller, A., Andruh, M.: Extended structures constructed from alkoxo-bridged binuclear complexes as nodes and bis(4-pyridyl) ethylene as a spacer. CRYSTAL GROWTH & DESIGN. 5, 279-282 (2005).
Marin, G, Tudor, V, Kravtsov, V. C., Schmidtmann, Marc, Simonov, Y. A., Müller, Achim, and Andruh, Marius. “Extended structures constructed from alkoxo-bridged binuclear complexes as nodes and bis(4-pyridyl) ethylene as a spacer”. CRYSTAL GROWTH & DESIGN 5.1 (2005): 279-282.
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