Energy transfer in the OH A(2)Sigma(+) state: The role of polarization and of multi-quantum energy transfer

Brockhinke A, Lenhard U, Bulter A, Kohse-Höinghaus K (2005)
PHYSICAL CHEMISTRY CHEMICAL PHYSICS 7(5): 874-881.

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Energy transfer in the excited state of molecules including quenching, rotational and vibrational energy transfer, and polarization scrambling is one of the major factors which limit the accuracy of laser-induced fluorescence (LIF) measurements. In this contribution, we present time-, wavelength-, and polarization-resolved spectra of OH in a stoichiometric H-2/air flame at atmospheric pressure. Emphasis is placed on the investigation of the role of polarization effects and of multi-quantum vibrational energy transfer on fluorescence spectra originating from the OH A(2)Sigma(+) state. Results are compared to simulations using a rate-equation model (LASKIN) developed in our group.
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Brockhinke A, Lenhard U, Bulter A, Kohse-Höinghaus K. Energy transfer in the OH A(2)Sigma(+) state: The role of polarization and of multi-quantum energy transfer. PHYSICAL CHEMISTRY CHEMICAL PHYSICS. 2005;7(5):874-881.
Brockhinke, A., Lenhard, U., Bulter, A., & Kohse-Höinghaus, K. (2005). Energy transfer in the OH A(2)Sigma(+) state: The role of polarization and of multi-quantum energy transfer. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 7(5), 874-881.
Brockhinke, A., Lenhard, U., Bulter, A., and Kohse-Höinghaus, K. (2005). Energy transfer in the OH A(2)Sigma(+) state: The role of polarization and of multi-quantum energy transfer. PHYSICAL CHEMISTRY CHEMICAL PHYSICS 7, 874-881.
Brockhinke, A., et al., 2005. Energy transfer in the OH A(2)Sigma(+) state: The role of polarization and of multi-quantum energy transfer. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 7(5), p 874-881.
A. Brockhinke, et al., “Energy transfer in the OH A(2)Sigma(+) state: The role of polarization and of multi-quantum energy transfer”, PHYSICAL CHEMISTRY CHEMICAL PHYSICS, vol. 7, 2005, pp. 874-881.
Brockhinke, A., Lenhard, U., Bulter, A., Kohse-Höinghaus, K.: Energy transfer in the OH A(2)Sigma(+) state: The role of polarization and of multi-quantum energy transfer. PHYSICAL CHEMISTRY CHEMICAL PHYSICS. 7, 874-881 (2005).
Brockhinke, Andreas, Lenhard, Ulrich, Bulter, Andreas, and Kohse-Höinghaus, Katharina. “Energy transfer in the OH A(2)Sigma(+) state: The role of polarization and of multi-quantum energy transfer”. PHYSICAL CHEMISTRY CHEMICAL PHYSICS 7.5 (2005): 874-881.
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Differential and integral cross sections in OH(X) + Xe collisions.
Sarma G, Saha AK, ter Meulen JJ, Parker DH, Marinakis S., J Chem Phys 142(3), 2015
PMID: 25612711

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