Energy transfer in the OH A(2)Sigma(+) state: The role of polarization and of multi-quantum energy transfer

Brockhinke A, Lenhard U, Bulter A, Kohse-Höinghaus K (2005)
PHYSICAL CHEMISTRY CHEMICAL PHYSICS 7(5): 874-881.

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Journal Article | Original Article | Published | English

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Fakultät für Chemie > Physikalische Chemie I
Abstract
Energy transfer in the excited state of molecules including quenching, rotational and vibrational energy transfer, and polarization scrambling is one of the major factors which limit the accuracy of laser-induced fluorescence (LIF) measurements. In this contribution, we present time-, wavelength-, and polarization-resolved spectra of OH in a stoichiometric H-2/air flame at atmospheric pressure. Emphasis is placed on the investigation of the role of polarization effects and of multi-quantum vibrational energy transfer on fluorescence spectra originating from the OH A(2)Sigma(+) state. Results are compared to simulations using a rate-equation model (LASKIN) developed in our group.
Publishing Year
2005
ISSN
1463-9076
eISSN
1463-9084
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Brockhinke A, Lenhard U, Bulter A, Kohse-Höinghaus K. Energy transfer in the OH A(2)Sigma(+) state: The role of polarization and of multi-quantum energy transfer. PHYSICAL CHEMISTRY CHEMICAL PHYSICS. 2005;7(5):874-881.
Brockhinke, A., Lenhard, U., Bulter, A., & Kohse-Höinghaus, K. (2005). Energy transfer in the OH A(2)Sigma(+) state: The role of polarization and of multi-quantum energy transfer. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 7(5), 874-881. doi:10.1039/b415637d
Brockhinke, A., Lenhard, U., Bulter, A., and Kohse-Höinghaus, K. (2005). Energy transfer in the OH A(2)Sigma(+) state: The role of polarization and of multi-quantum energy transfer. PHYSICAL CHEMISTRY CHEMICAL PHYSICS 7, 874-881.
Brockhinke, A., et al., 2005. Energy transfer in the OH A(2)Sigma(+) state: The role of polarization and of multi-quantum energy transfer. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 7(5), p 874-881.
A. Brockhinke, et al., “Energy transfer in the OH A(2)Sigma(+) state: The role of polarization and of multi-quantum energy transfer”, PHYSICAL CHEMISTRY CHEMICAL PHYSICS, vol. 7, 2005, pp. 874-881.
Brockhinke, A., Lenhard, U., Bulter, A., Kohse-Höinghaus, K.: Energy transfer in the OH A(2)Sigma(+) state: The role of polarization and of multi-quantum energy transfer. PHYSICAL CHEMISTRY CHEMICAL PHYSICS. 7, 874-881 (2005).
Brockhinke, Andreas, Lenhard, Ulrich, Bulter, Andreas, and Kohse-Höinghaus, Katharina. “Energy transfer in the OH A(2)Sigma(+) state: The role of polarization and of multi-quantum energy transfer”. PHYSICAL CHEMISTRY CHEMICAL PHYSICS 7.5 (2005): 874-881.
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Differential and integral cross sections in OH(X) + Xe collisions.
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PMID: 25612711

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