Lower rim functionalized chiral resorc[4]arenes derived from citronellal and carvone

Schiendorfer M, Mattay J (2005)
Synthesis (16): 2701-2712.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
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Abstract / Bemerkung
In our work we have provided the lower rim of resorc[4]arenes with stereogenic centers as well as with functional groups. For the synthesis of these lower rim functionalized chiral resorc[4]arenes we have used aldehydes derived front citronellal and carvone. In general, the functional group was introduced into the aldehyde compound prior to the final cyclization step. In the case of substitution of the functional group by chloride ions during the cyclization step under standard conditions (HCl-EtOH, Delta), hydrochloric acid was replaced by the conjugated acid of the functional group. Another strategy is the introduction of the iodo group at the lower rim of a resorc[4]arene, which can be easily substituted by good nucleophiles and mild bases without protection of the upper rim.
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Zeitschriftentitel
Synthesis
Zeitschriftennummer
16
Seite
2701-2712
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Schiendorfer M, Mattay J. Lower rim functionalized chiral resorc[4]arenes derived from citronellal and carvone. Synthesis. 2005;(16):2701-2712.
Schiendorfer, M., & Mattay, J. (2005). Lower rim functionalized chiral resorc[4]arenes derived from citronellal and carvone. Synthesis(16), 2701-2712. doi:10.1055/s-2005-872108
Schiendorfer, M., and Mattay, J. (2005). Lower rim functionalized chiral resorc[4]arenes derived from citronellal and carvone. Synthesis, 2701-2712.
Schiendorfer, M., & Mattay, J., 2005. Lower rim functionalized chiral resorc[4]arenes derived from citronellal and carvone. Synthesis, (16), p 2701-2712.
M. Schiendorfer and J. Mattay, “Lower rim functionalized chiral resorc[4]arenes derived from citronellal and carvone”, Synthesis, 2005, pp. 2701-2712.
Schiendorfer, M., Mattay, J.: Lower rim functionalized chiral resorc[4]arenes derived from citronellal and carvone. Synthesis. 2701-2712 (2005).
Schiendorfer, Michael, and Mattay, Jochen. “Lower rim functionalized chiral resorc[4]arenes derived from citronellal and carvone”. Synthesis 16 (2005): 2701-2712.