The first centrohexaindane bearing twelve functional groups at its outer molecular periphery and related lower veratrole-derived centropolyindanes

Harig M, Kuck D (2006)
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (7): 1647-1655.

Journal Article | Published | English

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The first T-d-symmetrical derivative of centrohexaindane bearing twelve functional groups has been synthesized. Six pairs of methoxy groups, each of which belong to six veratrole units fused to the topologically nonplanar (K-5) core, point outwards from the molecular center into the six directions of the Cartesian space. The synthesis of this first dodeca-substituted centrohexaindane was achieved along the "propellane route" established previously for the parent centrohexaindane, but the electron-rich character of some of the intermediates was found to require considerably modified methodology. Two hexamethoxy-substituted centrotriindanes, representing lower congeners of the title compound and bearing three veratrole units, were also synthesized. (c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006.
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Harig M, Kuck D. The first centrohexaindane bearing twelve functional groups at its outer molecular periphery and related lower veratrole-derived centropolyindanes. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY. 2006;(7):1647-1655.
Harig, M., & Kuck, D. (2006). The first centrohexaindane bearing twelve functional groups at its outer molecular periphery and related lower veratrole-derived centropolyindanes. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY(7), 1647-1655.
Harig, M., and Kuck, D. (2006). The first centrohexaindane bearing twelve functional groups at its outer molecular periphery and related lower veratrole-derived centropolyindanes. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 1647-1655.
Harig, M., & Kuck, D., 2006. The first centrohexaindane bearing twelve functional groups at its outer molecular periphery and related lower veratrole-derived centropolyindanes. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, (7), p 1647-1655.
M. Harig and D. Kuck, “The first centrohexaindane bearing twelve functional groups at its outer molecular periphery and related lower veratrole-derived centropolyindanes”, EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2006, pp. 1647-1655.
Harig, M., Kuck, D.: The first centrohexaindane bearing twelve functional groups at its outer molecular periphery and related lower veratrole-derived centropolyindanes. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY. 1647-1655 (2006).
Harig, M., and Kuck, Dietmar. “The first centrohexaindane bearing twelve functional groups at its outer molecular periphery and related lower veratrole-derived centropolyindanes”. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY 7 (2006): 1647-1655.
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