Synthesis of optically active (1R,4S,6S)-6-hydroxybicyclo[2.2.2]octan-2-one

Tzvetkov NT, Schmoldt P, Neumann B, Stammler H-G, Mattay J (2006)
TETRAHEDRON-ASYMMETRY 17(6): 993-998.

Journal Article | Published | English

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Bicyclo[2.2.2]octanone is an important building block for the synthesis of bioactive compounds and natural products. Herein, we present a new synthetic route for the formation of (1R, 4S, 6S)-6-hydroxybicyclo [2.2.2]octan-2-one derivatives via a catalytic asymmetric Michael reaction in high stereoselectivity and yields. (c) 2006 Elsevier Ltd. All rights reserved.
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Tzvetkov NT, Schmoldt P, Neumann B, Stammler H-G, Mattay J. Synthesis of optically active (1R,4S,6S)-6-hydroxybicyclo[2.2.2]octan-2-one. TETRAHEDRON-ASYMMETRY. 2006;17(6):993-998.
Tzvetkov, N. T., Schmoldt, P., Neumann, B., Stammler, H. - G., & Mattay, J. (2006). Synthesis of optically active (1R,4S,6S)-6-hydroxybicyclo[2.2.2]octan-2-one. TETRAHEDRON-ASYMMETRY, 17(6), 993-998.
Tzvetkov, N. T., Schmoldt, P., Neumann, B., Stammler, H. - G., and Mattay, J. (2006). Synthesis of optically active (1R,4S,6S)-6-hydroxybicyclo[2.2.2]octan-2-one. TETRAHEDRON-ASYMMETRY 17, 993-998.
Tzvetkov, N.T., et al., 2006. Synthesis of optically active (1R,4S,6S)-6-hydroxybicyclo[2.2.2]octan-2-one. TETRAHEDRON-ASYMMETRY, 17(6), p 993-998.
N.T. Tzvetkov, et al., “Synthesis of optically active (1R,4S,6S)-6-hydroxybicyclo[2.2.2]octan-2-one”, TETRAHEDRON-ASYMMETRY, vol. 17, 2006, pp. 993-998.
Tzvetkov, N.T., Schmoldt, P., Neumann, B., Stammler, H.-G., Mattay, J.: Synthesis of optically active (1R,4S,6S)-6-hydroxybicyclo[2.2.2]octan-2-one. TETRAHEDRON-ASYMMETRY. 17, 993-998 (2006).
Tzvetkov, Nikolay T., Schmoldt, Philip, Neumann, Beate, Stammler, Hans-Georg, and Mattay, Jochen. “Synthesis of optically active (1R,4S,6S)-6-hydroxybicyclo[2.2.2]octan-2-one”. TETRAHEDRON-ASYMMETRY 17.6 (2006): 993-998.
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