Formation of a "less stable" polyanion directed and protected by electrophilic internal surface functionalities of a capsule in growth: [{Mo6O19}(2-)subset of{(Mo72Fe30O252)-Fe-VI-O-III(ac)(20)(H2O)(92)}](4-)

Müller A, Todea AM, Bögge H, van Slageren J, Dressel M, Stammler A, Rusu M (2006)
CHEMICAL COMMUNICATIONS (29): 3066-3068.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
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Abstract / Bemerkung
The spherical capsule skeleton of the host - guest system [{Mo6O19}(2-)subset of{Mo-VI Fe-72(III) O-30(252)(CH3COO)(20)(H2O)(92)}](4-) 1a built up by 12 {( MoVI) MoVI 5} type pentagonal units linked by 30 Fe-III centers which span the unique icosahedral Archimedean solid, the icosidodecahedron - can now be constructed deliberately and with a simpler composition than before from an acidified aqueous molybdate solution containing the mentioned ( virtual) pentagonal units; the encapsulated hexamolybdate - normally not formed in water - is built up in an unprecedented way concomitant with capsule growth, while being directed by the corresponding internal electrophilic surface functionalities.
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CHEMICAL COMMUNICATIONS
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29
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3066-3068
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Müller A, Todea AM, Bögge H, et al. Formation of a "less stable" polyanion directed and protected by electrophilic internal surface functionalities of a capsule in growth: [{Mo6O19}(2-)subset of{(Mo72Fe30O252)-Fe-VI-O-III(ac)(20)(H2O)(92)}](4-). CHEMICAL COMMUNICATIONS. 2006;(29):3066-3068.
Müller, A., Todea, A. M., Bögge, H., van Slageren, J., Dressel, M., Stammler, A., & Rusu, M. (2006). Formation of a "less stable" polyanion directed and protected by electrophilic internal surface functionalities of a capsule in growth: [{Mo6O19}(2-)subset of{(Mo72Fe30O252)-Fe-VI-O-III(ac)(20)(H2O)(92)}](4-). CHEMICAL COMMUNICATIONS(29), 3066-3068. doi:10.1039/b604977j
Müller, A., Todea, A. M., Bögge, H., van Slageren, J., Dressel, M., Stammler, A., and Rusu, M. (2006). Formation of a "less stable" polyanion directed and protected by electrophilic internal surface functionalities of a capsule in growth: [{Mo6O19}(2-)subset of{(Mo72Fe30O252)-Fe-VI-O-III(ac)(20)(H2O)(92)}](4-). CHEMICAL COMMUNICATIONS, 3066-3068.
Müller, A., et al., 2006. Formation of a "less stable" polyanion directed and protected by electrophilic internal surface functionalities of a capsule in growth: [{Mo6O19}(2-)subset of{(Mo72Fe30O252)-Fe-VI-O-III(ac)(20)(H2O)(92)}](4-). CHEMICAL COMMUNICATIONS, (29), p 3066-3068.
A. Müller, et al., “Formation of a "less stable" polyanion directed and protected by electrophilic internal surface functionalities of a capsule in growth: [{Mo6O19}(2-)subset of{(Mo72Fe30O252)-Fe-VI-O-III(ac)(20)(H2O)(92)}](4-)”, CHEMICAL COMMUNICATIONS, 2006, pp. 3066-3068.
Müller, A., Todea, A.M., Bögge, H., van Slageren, J., Dressel, M., Stammler, A., Rusu, M.: Formation of a "less stable" polyanion directed and protected by electrophilic internal surface functionalities of a capsule in growth: [{Mo6O19}(2-)subset of{(Mo72Fe30O252)-Fe-VI-O-III(ac)(20)(H2O)(92)}](4-). CHEMICAL COMMUNICATIONS. 3066-3068 (2006).
Müller, Achim, Todea, Ana Maria, Bögge, Hartmut, van Slageren, Joris, Dressel, Martin, Stammler, Anja, and Rusu, Mariana. “Formation of a "less stable" polyanion directed and protected by electrophilic internal surface functionalities of a capsule in growth: [{Mo6O19}(2-)subset of{(Mo72Fe30O252)-Fe-VI-O-III(ac)(20)(H2O)(92)}](4-)”. CHEMICAL COMMUNICATIONS 29 (2006): 3066-3068.

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18 References

Daten bereitgestellt von Europe PubMed Central.


M?ller, Coord. Chem. Rev. 245(), 2003

Hall, Chem. Commun. (), 2003

M?ller, Chem. Commun. (), 1999

M?ller, Coord. Chem. Rev. 222(), 2001

M?ller, Angew. Chem., Int. Ed. 44(), 2005

Botar, Chem. Commun. (), 2005

M?ller, Angew. Chem., Int. Ed. 41(), 2002

M?ller, Angew. Chem., Int. Ed. 38(), 1999

Gatteschi, Europhys. News 34(6 (Magnetism Sp), 2003

M?ller, ChemPhysChem 2(), 2001

Schr?der, Phys. Rev. Lett. 94(017205), 2005

C?pas, Prog. Theor. Phys. Suppl. 159(), 2005
Strong attraction among the fully hydrophilic {Mo72Fe30} macroanions.
Liu G, Liu T., J. Am. Chem. Soc. 127(19), 2005
PMID: 15884924
Polyoxometalates: Very Large Clusters-Nanoscale Magnets.
Muller A, Peters F, Pope MT, Gatteschi D., Chem. Rev. 98(1), 1998
PMID: 11851505

Krebs, Acta Crystallogr., Sect. B 38(), 1982

Botar, Chem. Commun. (), 2005

Greedan, J. Mater. Chem. 11(), 2001

Narumi, Europhys. Lett. 65(), 2004

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