Formation of a "less stable" polyanion directed and protected by electrophilic internal surface functionalities of a capsule in growth: [{Mo6O19}(2-)subset of{(Mo72Fe30O252)-Fe-VI-O-III(ac)(20)(H2O)(92)}](4-)

Müller A, Todea AM, Bögge H, van Slageren J, Dressel M, Stammler A, Rusu M (2006)
CHEMICAL COMMUNICATIONS (29): 3066-3068.

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The spherical capsule skeleton of the host - guest system [{Mo6O19}(2-)subset of{Mo-VI Fe-72(III) O-30(252)(CH3COO)(20)(H2O)(92)}](4-) 1a built up by 12 {( MoVI) MoVI 5} type pentagonal units linked by 30 Fe-III centers which span the unique icosahedral Archimedean solid, the icosidodecahedron - can now be constructed deliberately and with a simpler composition than before from an acidified aqueous molybdate solution containing the mentioned ( virtual) pentagonal units; the encapsulated hexamolybdate - normally not formed in water - is built up in an unprecedented way concomitant with capsule growth, while being directed by the corresponding internal electrophilic surface functionalities.
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Müller A, Todea AM, Bögge H, et al. Formation of a "less stable" polyanion directed and protected by electrophilic internal surface functionalities of a capsule in growth: [{Mo6O19}(2-)subset of{(Mo72Fe30O252)-Fe-VI-O-III(ac)(20)(H2O)(92)}](4-). CHEMICAL COMMUNICATIONS. 2006;(29):3066-3068.
Müller, A., Todea, A. M., Bögge, H., van Slageren, J., Dressel, M., Stammler, A., & Rusu, M. (2006). Formation of a "less stable" polyanion directed and protected by electrophilic internal surface functionalities of a capsule in growth: [{Mo6O19}(2-)subset of{(Mo72Fe30O252)-Fe-VI-O-III(ac)(20)(H2O)(92)}](4-). CHEMICAL COMMUNICATIONS(29), 3066-3068.
Müller, A., Todea, A. M., Bögge, H., van Slageren, J., Dressel, M., Stammler, A., and Rusu, M. (2006). Formation of a "less stable" polyanion directed and protected by electrophilic internal surface functionalities of a capsule in growth: [{Mo6O19}(2-)subset of{(Mo72Fe30O252)-Fe-VI-O-III(ac)(20)(H2O)(92)}](4-). CHEMICAL COMMUNICATIONS, 3066-3068.
Müller, A., et al., 2006. Formation of a "less stable" polyanion directed and protected by electrophilic internal surface functionalities of a capsule in growth: [{Mo6O19}(2-)subset of{(Mo72Fe30O252)-Fe-VI-O-III(ac)(20)(H2O)(92)}](4-). CHEMICAL COMMUNICATIONS, (29), p 3066-3068.
A. Müller, et al., “Formation of a "less stable" polyanion directed and protected by electrophilic internal surface functionalities of a capsule in growth: [{Mo6O19}(2-)subset of{(Mo72Fe30O252)-Fe-VI-O-III(ac)(20)(H2O)(92)}](4-)”, CHEMICAL COMMUNICATIONS, 2006, pp. 3066-3068.
Müller, A., Todea, A.M., Bögge, H., van Slageren, J., Dressel, M., Stammler, A., Rusu, M.: Formation of a "less stable" polyanion directed and protected by electrophilic internal surface functionalities of a capsule in growth: [{Mo6O19}(2-)subset of{(Mo72Fe30O252)-Fe-VI-O-III(ac)(20)(H2O)(92)}](4-). CHEMICAL COMMUNICATIONS. 3066-3068 (2006).
Müller, Achim, Todea, Ana Maria, Bögge, Hartmut, van Slageren, Joris, Dressel, Martin, Stammler, Anja, and Rusu, Mariana. “Formation of a "less stable" polyanion directed and protected by electrophilic internal surface functionalities of a capsule in growth: [{Mo6O19}(2-)subset of{(Mo72Fe30O252)-Fe-VI-O-III(ac)(20)(H2O)(92)}](4-)”. CHEMICAL COMMUNICATIONS 29 (2006): 3066-3068.
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Polyoxotungstates now also with pentagonal units: supramolecular chemistry and tuning of magnetic exchange in {(M)M5}12V30 Keplerates (M = Mo, W).
Todea AM, Merca A, Bogge H, Glaser T, Engelhardt L, Prozorov R, Luban M, Muller A., Chem. Commun. (Camb.) (23), 2009
PMID: 19503867

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