Synthesis of a benzoannelated spheriphane (globular cyclophane) on the way to potential precursors of C-60-fullerene

Nierle J, Kuck D (2006)
SYNLETT 2006(18): 2914-2920.

Journal Article | Published | English

No fulltext has been uploaded

Author
;
Abstract
A viable route to the novel globular cyclophane 2, a C48H36-spheriphane, is presented as a result of our research aimed at the synthesis of the hypothetical deciphenyl 3, a C60H36-sphcriphane, which has been envisaged as a potential precursor to C-60-fullerene. Several syntheses of the key intermediate of the route to 2, viz. septiphenyl 13 (C48H42), a sterically crowded 1,3,5-tris(ortho-biphenylyl)benzene derivative, are described. These include threefold Heck coupling and related threefold Pd(0)-catalyzed C-C cross-coupling reactions, as well as threefold benzoannelation involving tetrachlorothiophene-S,S-dioxide and PET-induced dehalogenation of highly chlorinated septiphenyl derivatives.
Publishing Year
ISSN
eISSN
PUB-ID

Cite this

Nierle J, Kuck D. Synthesis of a benzoannelated spheriphane (globular cyclophane) on the way to potential precursors of C-60-fullerene. SYNLETT. 2006;2006(18):2914-2920.
Nierle, J., & Kuck, D. (2006). Synthesis of a benzoannelated spheriphane (globular cyclophane) on the way to potential precursors of C-60-fullerene. SYNLETT, 2006(18), 2914-2920.
Nierle, J., and Kuck, D. (2006). Synthesis of a benzoannelated spheriphane (globular cyclophane) on the way to potential precursors of C-60-fullerene. SYNLETT 2006, 2914-2920.
Nierle, J., & Kuck, D., 2006. Synthesis of a benzoannelated spheriphane (globular cyclophane) on the way to potential precursors of C-60-fullerene. SYNLETT, 2006(18), p 2914-2920.
J. Nierle and D. Kuck, “Synthesis of a benzoannelated spheriphane (globular cyclophane) on the way to potential precursors of C-60-fullerene”, SYNLETT, vol. 2006, 2006, pp. 2914-2920.
Nierle, J., Kuck, D.: Synthesis of a benzoannelated spheriphane (globular cyclophane) on the way to potential precursors of C-60-fullerene. SYNLETT. 2006, 2914-2920 (2006).
Nierle, Jens, and Kuck, Dietmar. “Synthesis of a benzoannelated spheriphane (globular cyclophane) on the way to potential precursors of C-60-fullerene”. SYNLETT 2006.18 (2006): 2914-2920.
This data publication is cited in the following publications:
This publication cites the following data publications:

Export

0 Marked Publications

Open Data PUB

Web of Science

View record in Web of Science®

Search this title in

Google Scholar