Photochemical single-molecule affinity switch

Schäfer C, Eckel R, Ros R, Mattay J, Anselmetti D (2007)
Journal of the American Chemical Society 129(6): 1488-1489.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
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Abstract / Bemerkung
Manipulation and control at the molecular level is a prerequisite for future nanomachines and nanodevices. In order to build a bistable molecular affinity switch, we have synthesized a supramolecular guest-host system whose binding affinity can externally be controlled and repetitively switched by UV light or heating. This photochemical macrocycle, which incorporates a supramolecular resorc[4] arene receptor cavity and two photodimerizable anthracene moieties, has been investigated by single-molecule force spectroscopy under external optical control which proved the repetitive and selective activation and deactivation at the level of individual molecular complexes. This synthetic photochemical single-molecule reaction acts as an intermolecular switch and can be affinity-tuned under external control, which allows new concepts for directed molecular assembly and motional functionalities at the nanoscale in the future.
Erscheinungsjahr
Zeitschriftentitel
Journal of the American Chemical Society
Band
129
Zeitschriftennummer
6
Seite
1488-1489
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Schäfer C, Eckel R, Ros R, Mattay J, Anselmetti D. Photochemical single-molecule affinity switch. Journal of the American Chemical Society. 2007;129(6):1488-1489.
Schäfer, C., Eckel, R., Ros, R., Mattay, J., & Anselmetti, D. (2007). Photochemical single-molecule affinity switch. Journal of the American Chemical Society, 129(6), 1488-1489. doi:10.1021/ja067734h
Schäfer, C., Eckel, R., Ros, R., Mattay, J., and Anselmetti, D. (2007). Photochemical single-molecule affinity switch. Journal of the American Chemical Society 129, 1488-1489.
Schäfer, C., et al., 2007. Photochemical single-molecule affinity switch. Journal of the American Chemical Society, 129(6), p 1488-1489.
C. Schäfer, et al., “Photochemical single-molecule affinity switch”, Journal of the American Chemical Society, vol. 129, 2007, pp. 1488-1489.
Schäfer, C., Eckel, R., Ros, R., Mattay, J., Anselmetti, D.: Photochemical single-molecule affinity switch. Journal of the American Chemical Society. 129, 1488-1489 (2007).
Schäfer, Christian, Eckel, Rainer, Ros, Robert, Mattay, Jochen, and Anselmetti, Dario. “Photochemical single-molecule affinity switch”. Journal of the American Chemical Society 129.6 (2007): 1488-1489.

29 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

Synthesis of compounds presenting three and four anthracene units as potential connectors to mediate infinite lateral growth at the air/water interface.
Münzenberg C, Rossi A, Feldman K, Fiolka R, Stemmer A, Kita-Tokarczyk K, Meier W, Sakamoto J, Lukin O, Schlüter AD., Chemistry 14(34), 2008
PMID: 18942696
Molecular machines working on surfaces and at interfaces.
Balzani V, Credi A, Venturi M., Chemphyschem 9(2), 2008
PMID: 18085722
Photocyclizable resorcin[4]arene dimers.
Schäfer C, Strübe F, Bringmann S, Mattay J., Photochem Photobiol Sci 7(12), 2008
PMID: 19037497

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