Photochemical single-molecule affinity switch

Schaefer C, Eckel R, Ros R, Mattay J, Anselmetti D (2007)
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 129(6): 1488-1489.

Journal Article | Published | English

No fulltext has been uploaded

Author
; ; ; ;
Abstract
Manipulation and control at the molecular level is a prerequisite for future nanomachines and nanodevices. In order to build a bistable molecular affinity switch, we have synthesized a supramolecular guest-host system whose binding affinity can externally be controlled and repetitively switched by UV light or heating. This photochemical macrocycle, which incorporates a supramolecular resorc[4] arene receptor cavity and two photodimerizable anthracene moieties, has been investigated by single-molecule force spectroscopy under external optical control which proved the repetitive and selective activation and deactivation at the level of individual molecular complexes. This synthetic photochemical single-molecule reaction acts as an intermolecular switch and can be affinity-tuned under external control, which allows new concepts for directed molecular assembly and motional functionalities at the nanoscale in the future.
Publishing Year
ISSN
eISSN
PUB-ID

Cite this

Schaefer C, Eckel R, Ros R, Mattay J, Anselmetti D. Photochemical single-molecule affinity switch. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 2007;129(6):1488-1489.
Schaefer, C., Eckel, R., Ros, R., Mattay, J., & Anselmetti, D. (2007). Photochemical single-molecule affinity switch. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 129(6), 1488-1489.
Schaefer, C., Eckel, R., Ros, R., Mattay, J., and Anselmetti, D. (2007). Photochemical single-molecule affinity switch. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 129, 1488-1489.
Schaefer, C., et al., 2007. Photochemical single-molecule affinity switch. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 129(6), p 1488-1489.
C. Schaefer, et al., “Photochemical single-molecule affinity switch”, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 129, 2007, pp. 1488-1489.
Schaefer, C., Eckel, R., Ros, R., Mattay, J., Anselmetti, D.: Photochemical single-molecule affinity switch. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 129, 1488-1489 (2007).
Schaefer, Christian, Eckel, Rainer, Ros, Robert, Mattay, Jochen, and Anselmetti, Dario. “Photochemical single-molecule affinity switch”. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 129.6 (2007): 1488-1489.
This data publication is cited in the following publications:
This publication cites the following data publications:

18 Citations in Europe PMC

Data provided by Europe PubMed Central.

Anthracene photodimerization in a bis-chromophoric hydrogen-bonding receptor.
Liang CK, Desvergne JP, Bassani DM., Photochem. Photobiol. Sci. 13(2), 2014
PMID: 24276577
Reversible control over molecular recognition in surface-bound photoswitchable hydrogen-bonding receptors: towards read-write-erase molecular printboards.
Liang CK, Dubacheva GV, Buffeteau T, Cavagnat D, Hapiot P, Fabre B, Tucker JH, Bassani DM., Chemistry 19(38), 2013
PMID: 23929495
Analysis of DNA interactions using single-molecule force spectroscopy.
Ritzefeld M, Walhorn V, Anselmetti D, Sewald N., Amino Acids 44(6), 2013
PMID: 23468137
Binary DNA nanostructures for data encryption.
Halvorsen K, Wong WP., PLoS ONE 7(9), 2012
PMID: 22984477
Reconstructing the free-energy landscape associated to molecular motors processivity.
Lopez Alamilla NJ, Santamaria Holek I., Biophys. Chem. 167(), 2012
PMID: 22659574
Photophysics Applied to Cavitands and Capsules.
Berryman OB, Dube H, Rebek J Jr., Isr. J. Chem. 51(7), 2011
PMID: 24009399
Functional characterization of a supramolecular affinity switch at the single molecule level.
Walhorn V, Schafer C, Schroder T, Mattay J, Anselmetti D., Nanoscale 3(11), 2011
PMID: 22009325
Anthracene-resorcin[4]arene-based capsules: synthesis and photoswitchable features.
Bringmann S, Brodbeck R, Hartmann R, Schafer C, Mattay J., Org. Biomol. Chem. 9(21), 2011
PMID: 21927749
A photoinduced pH jump applied to drug release from cucurbit[7]uril.
Carvalho CP, Uzunova VD, Da Silva JP, Nau WM, Pischel U., Chem. Commun. (Camb.) 47(31), 2011
PMID: 21735013
Viable route for switching of an engineered silica surface using Cu2+ ions at sub-ppm levels.
Lupo F, Gentile S, Ballistreri FP, Tomaselli GA, Fragala ME, Gulino A., Analyst 135(9), 2010
PMID: 20676437
Single-molecule force spectroscopy of supramolecular heterodimeric capsules.
Schroder T, Geisler T, Walhorn V, Schnatwinkel B, Anselmetti D, Mattay J., Phys Chem Chem Phys 12(36), 2010
PMID: 20661519
Photochromic resorcin[4]arenes: stabilization of intramolecular anthracene dimers in solution.
Schafer C, Rozhenko AB, Mattay J., Photochem. Photobiol. Sci. 8(8), 2009
PMID: 19639122
Photocyclizable resorcin[4]arene dimers.
Schafer C, Strube F, Bringmann S, Mattay J., Photochem. Photobiol. Sci. 7(12), 2008
PMID: 19037497
Synthesis of compounds presenting three and four anthracene units as potential connectors to mediate infinite lateral growth at the air/water interface.
Munzenberg C, Rossi A, Feldman K, Fiolka R, Stemmer A, Kita-Tokarczyk K, Meier W, Sakamoto J, Lukin O, Schluter AD., Chemistry 14(34), 2008
PMID: 18942696
A kinetic study of guest displacement reactions on a host-guest complex with a photoswitchable calixarene.
Letzel MC, Schafer C, Novara FR, Speranza M, Rozhenko AB, Schoeller WW, Mattay J., J Mass Spectrom 43(11), 2008
PMID: 18698554
Molecular machines working on surfaces and at interfaces.
Balzani V, Credi A, Venturi M., Chemphyschem 9(2), 2008
PMID: 18085722

Export

0 Marked Publications

Open Data PUB

Web of Science

View record in Web of Science®

Sources

PMID: 17249675
PubMed | Europe PMC

Search this title in

Google Scholar