Syntheses and structures of (N ',N '-dimethylhydrazido)silanes

Gronde I, Neumann B, Willner A, Pape T, Mitzel NW (2009)
DALTON TRANSACTIONS (27): 5300-5309.

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Abstract
The hydrazidosilanes Ph2Si(NHNMe2)(2) (1), Me2Si(NHNMe2)(2) (2), PhSi(NHNMe2)(3) (3), MeSi(NHNMe2)(3) (4), PhClSi(NHNMe2)(2) (5), MeClSi(NHNMe2)(2) (6), Me2ClSi(NHNMe2) (7), MeClHSi(NHNMe2) (8), MeHSi(NHNMe2)(2) (9), Me2HSi(NHNMe2) (10), Me2NN[HSi(NHNMe2)(2)](2) (11) and Si(NHNMe2)(4) (12) have been prepared by the reaction of the corresponding chlorosilanes with N,N-dimethylhydrazine. Some of the compounds containing Si-Cl and N-H functions simultaneously (6, 7, 8) are very reactive and tend to polymerise and could only be characterised by spectroscopic methods (H-1, C-13, Si-29 NMR, IR, MS). All other compounds could additionally be characterised by elemental analyses. The structures of 1, 2, 5, 9, 11 and 12 in the solid state were determined by X-ray diffraction. These include the first structural determinations of compounds containing SiH-NH-N (9, 11) and SiCl-NH-N (5) units.
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Gronde I, Neumann B, Willner A, Pape T, Mitzel NW. Syntheses and structures of (N ',N '-dimethylhydrazido)silanes. DALTON TRANSACTIONS. 2009;(27):5300-5309.
Gronde, I., Neumann, B., Willner, A., Pape, T., & Mitzel, N. W. (2009). Syntheses and structures of (N ',N '-dimethylhydrazido)silanes. DALTON TRANSACTIONS(27), 5300-5309.
Gronde, I., Neumann, B., Willner, A., Pape, T., and Mitzel, N. W. (2009). Syntheses and structures of (N ',N '-dimethylhydrazido)silanes. DALTON TRANSACTIONS, 5300-5309.
Gronde, I., et al., 2009. Syntheses and structures of (N ',N '-dimethylhydrazido)silanes. DALTON TRANSACTIONS, (27), p 5300-5309.
I. Gronde, et al., “Syntheses and structures of (N ',N '-dimethylhydrazido)silanes”, DALTON TRANSACTIONS, 2009, pp. 5300-5309.
Gronde, I., Neumann, B., Willner, A., Pape, T., Mitzel, N.W.: Syntheses and structures of (N ',N '-dimethylhydrazido)silanes. DALTON TRANSACTIONS. 5300-5309 (2009).
Gronde, Ingo, Neumann, Beate, Willner, Alexander, Pape, Tania, and Mitzel, Norbert W. “Syntheses and structures of (N ',N '-dimethylhydrazido)silanes”. DALTON TRANSACTIONS 27 (2009): 5300-5309.
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