An Organozinc Hydrazide-Thiolate Aggregate with a Zn3N4S2 Core

Surajit J, Mitzel NW (2009)
ZEITSCHRIFT FÜR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 64(3): 339-342.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
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Abstract / Bemerkung
The first organometallic zinc hydrazide-thiolate cluster, [(MeZn)(2)(PhSZn)(HNNMe2)(H2N-NMe2)(SPh)(2)](2) (1) has been prepared by alkane elimination from dimethylzinc solutions upon treatment with N,N-dimethylhydrazine and thiophenol and characterised by NMR spectroscopy, elemental analysis and single crystal X-ray diffraction. Compound I forms asymmetric aggregates containing a Nz(3)N(4)S(2) core. The core features rings with different connectivities. A seven-membered ZnSZnNNZnS ring comprises three five-membered rings, two of it ZnSZnNN and one of a ZnNZnNN atom sequence. Intermolecular S center dot center dot center dot H bonding is observed in the crystal.
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Zeitschriftentitel
ZEITSCHRIFT FÜR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
Band
64
Zeitschriftennummer
3
Seite
339-342
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Surajit J, Mitzel NW. An Organozinc Hydrazide-Thiolate Aggregate with a Zn3N4S2 Core. ZEITSCHRIFT FÜR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES. 2009;64(3):339-342.
Surajit, J., & Mitzel, N. W. (2009). An Organozinc Hydrazide-Thiolate Aggregate with a Zn3N4S2 Core. ZEITSCHRIFT FÜR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 64(3), 339-342. doi:10.1515/znb-2009-0316
Surajit, J., and Mitzel, N. W. (2009). An Organozinc Hydrazide-Thiolate Aggregate with a Zn3N4S2 Core. ZEITSCHRIFT FÜR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 64, 339-342.
Surajit, J., & Mitzel, N.W., 2009. An Organozinc Hydrazide-Thiolate Aggregate with a Zn3N4S2 Core. ZEITSCHRIFT FÜR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 64(3), p 339-342.
J. Surajit and N.W. Mitzel, “An Organozinc Hydrazide-Thiolate Aggregate with a Zn3N4S2 Core”, ZEITSCHRIFT FÜR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, vol. 64, 2009, pp. 339-342.
Surajit, J., Mitzel, N.W.: An Organozinc Hydrazide-Thiolate Aggregate with a Zn3N4S2 Core. ZEITSCHRIFT FÜR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES. 64, 339-342 (2009).
Surajit, Jana, and Mitzel, Norbert W. “An Organozinc Hydrazide-Thiolate Aggregate with a Zn3N4S2 Core”. ZEITSCHRIFT FÜR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 64.3 (2009): 339-342.