Synthesis, Structure, and Reactivity of Rhodium Bipyridine Compounds: Formation of a Rh-II Hydrido Cluster and a Rh-III Peroxido Complex

Penner A, Schröder T, Braun T, Ziemer B (2009)
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2009(29-30): 4464-4470.

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Abstract
Treatment of [Rh(mu-Cl)(coe)(2)](2) (coe = cyclooctene) with 4,4'-di-tert-butyl-2-2'-bibyridine (tbbpy) gives the bipyridine complex [Rh(Cl)(tbbpy)(coe)] (1) A subsequent reaction with dihydrogen results in the formation of the cluster [{Rh(Cl)(H)-(tbbpy)}](4) (2). The reaction of [Rh(mu-Cl)(coe)(2)](2) with tbbpy mthf followed by the addition of CNtBu affords [Rh(Cl)(tbbpy)-(CNtBu)] (3). The latter reacts with O-2 or O-18(2) to yield the peroxido complexes [Rh(Cl)(O-2)(tbbpy)(CNtBu)] (4a) and [Rh(Cl)(O-18(2))(tbbpy)-(CNtBu)) (4b), respectively. Complexes 1-4 were characterized by X-ray Crystallography ((C) Wiley-VCH Verlag GmbH & Co KGaA, 69451 Weinheim, Germany, 2009)
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Penner A, Schröder T, Braun T, Ziemer B. Synthesis, Structure, and Reactivity of Rhodium Bipyridine Compounds: Formation of a Rh-II Hydrido Cluster and a Rh-III Peroxido Complex. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2009;2009(29-30):4464-4470.
Penner, A., Schröder, T., Braun, T., & Ziemer, B. (2009). Synthesis, Structure, and Reactivity of Rhodium Bipyridine Compounds: Formation of a Rh-II Hydrido Cluster and a Rh-III Peroxido Complex. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2009(29-30), 4464-4470.
Penner, A., Schröder, T., Braun, T., and Ziemer, B. (2009). Synthesis, Structure, and Reactivity of Rhodium Bipyridine Compounds: Formation of a Rh-II Hydrido Cluster and a Rh-III Peroxido Complex. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2009, 4464-4470.
Penner, A., et al., 2009. Synthesis, Structure, and Reactivity of Rhodium Bipyridine Compounds: Formation of a Rh-II Hydrido Cluster and a Rh-III Peroxido Complex. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2009(29-30), p 4464-4470.
A. Penner, et al., “Synthesis, Structure, and Reactivity of Rhodium Bipyridine Compounds: Formation of a Rh-II Hydrido Cluster and a Rh-III Peroxido Complex”, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, vol. 2009, 2009, pp. 4464-4470.
Penner, A., Schröder, T., Braun, T., Ziemer, B.: Synthesis, Structure, and Reactivity of Rhodium Bipyridine Compounds: Formation of a Rh-II Hydrido Cluster and a Rh-III Peroxido Complex. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2009, 4464-4470 (2009).
Penner, Anna, Schröder, Tobias, Braun, Thomas, and Ziemer, Burkhard. “Synthesis, Structure, and Reactivity of Rhodium Bipyridine Compounds: Formation of a Rh-II Hydrido Cluster and a Rh-III Peroxido Complex”. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2009.29-30 (2009): 4464-4470.
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