Unveiling the Transient Template in the Self-Assembly of a Molecular Oxide Nanowheel

Miras HN, Cooper GJT, Long D-L, Bögge H, Müller A, Streb C, Cronin L (2010)
SCIENCE 327(5961): 72-74.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
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Abstract / Bemerkung
Self-assembly has proven a powerful means of preparing structurally intricate nanomaterials, but the mechanism is often masked by the common one-pot mixing procedure. We employed a flow system to study the steps underlying assembly of a previously characterized molybdenum oxide wheel 3.6 nanometers in diameter. We observed crystallization of an intermediate structure in which a central {Mo-36} cluster appears to template the assembly of the surrounding {Mo-150} wheel. The transient nature of the template is demonstrated by its ejection after the wheel is reduced to its final electronic state. The template's role in the self-assembly mechanism is further confirmed by the deliberate addition of the template to the reaction mixture, which greatly accelerates the assembly time of the {Mo-150} wheel and increases the yield.
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SCIENCE
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327
Ausgabe
5961
Seite(n)
72-74
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Miras HN, Cooper GJT, Long D-L, et al. Unveiling the Transient Template in the Self-Assembly of a Molecular Oxide Nanowheel. SCIENCE. 2010;327(5961):72-74.
Miras, H. N., Cooper, G. J. T., Long, D. - L., Bögge, H., Müller, A., Streb, C., & Cronin, L. (2010). Unveiling the Transient Template in the Self-Assembly of a Molecular Oxide Nanowheel. SCIENCE, 327(5961), 72-74. doi:10.1126/science.1181735
Miras, H. N., Cooper, G. J. T., Long, D. - L., Bögge, H., Müller, A., Streb, C., and Cronin, L. (2010). Unveiling the Transient Template in the Self-Assembly of a Molecular Oxide Nanowheel. SCIENCE 327, 72-74.
Miras, H.N., et al., 2010. Unveiling the Transient Template in the Self-Assembly of a Molecular Oxide Nanowheel. SCIENCE, 327(5961), p 72-74.
H.N. Miras, et al., “Unveiling the Transient Template in the Self-Assembly of a Molecular Oxide Nanowheel”, SCIENCE, vol. 327, 2010, pp. 72-74.
Miras, H.N., Cooper, G.J.T., Long, D.-L., Bögge, H., Müller, A., Streb, C., Cronin, L.: Unveiling the Transient Template in the Self-Assembly of a Molecular Oxide Nanowheel. SCIENCE. 327, 72-74 (2010).
Miras, Haralampos N., Cooper, Geoffrey J. T., Long, De-Liang, Bögge, Hartmut, Müller, Achim, Streb, Carsten, and Cronin, Leroy. “Unveiling the Transient Template in the Self-Assembly of a Molecular Oxide Nanowheel”. SCIENCE 327.5961 (2010): 72-74.

70 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

Stereoselective Assembly of Gigantic Chiral Molybdenum Blue Wheels Using Lanthanide Ions and Amino Acids.
Xuan W, Pow R, Watfa N, Zheng Q, Surman AJ, Long DL, Cronin L., J Am Chem Soc 141(3), 2019
PMID: 30495944
Elimination-Fusion Self-Assembly of a Nanometer-Scale 72-Nucleus Silver Cluster Caging a Pair of [EuW10 O36 ]9- Polyoxometalates.
Zhang SS, Su HF, Wang Z, Wang XP, Chen WX, Zhao QQ, Tung CH, Sun D, Zheng LS., Chemistry 24(8), 2018
PMID: 29243864
Wheel-to-rhomboid isomerization as well as nitrene transfer catalysis of ruthenium-thiolate wheels.
Tso KC, Chan SL, Huang JS, Che CM., Chem Commun (Camb) 53(16), 2017
PMID: 28120972
Coding the Assembly of Polyoxotungstates with a Programmable Reaction System.
Ruiz de la Oliva A, Sans V, Miras HN, Long DL, Cronin L., Inorg Chem 56(9), 2017
PMID: 28414229
Semiconductive Nanotube Array Constructed from Giant [Pb(II)18I54(I2)9] Wheel Clusters.
Wang GE, Xu G, Liu BW, Wang MS, Yao MS, Guo GC., Angew Chem Int Ed Engl 55(2), 2016
PMID: 26549327
A highly aluminum-doped β-isomer Keggin-type tungstoaluminate.
Han Z, Zhang H, Yan J, Zhai X., Dalton Trans 45(36), 2016
PMID: 27549221
Closing Uranyl Polyoxometalate Capsules with Bismuth and Lead Polyoxocations.
Renier O, Falaise C, Neal H, Kozma K, Nyman M., Angew Chem Int Ed Engl 55(43), 2016
PMID: 27672003
Geometrically restricted intermediates in the self-assembly of an M12L24 cuboctahedral complex.
Fujita D, Yokoyama H, Ueda Y, Sato S, Fujita M., Angew Chem Int Ed Engl 54(1), 2015
PMID: 25381901
Atom-precise polyoxometalate-ag2 s core-shell nanoparticles.
Li XY, Tan YZ, Yu K, Wang XP, Zhao YQ, Sun D, Zheng LS., Chem Asian J 10(6), 2015
PMID: 25852043
A new family of anionic organic-inorganic hybrid doughnut-like nanostructures.
Zhang Z, Gao WY, Wojtas L, Zhang Z, Zaworotko MJ., Chem Commun (Camb) 51(44), 2015
PMID: 25952958
Construction of Cluster Organic Frameworks with bnn Hexagonal BN Topologies.
Fang WH, Zhang L, Zhang J, Yang GY., Chemistry 21(44), 2015
PMID: 26346177
What molecular assembly can learn from catalytic chemistry.
Wang Y, Lin HX, Chen L, Ding SY, Lei ZC, Liu DY, Cao XY, Liang HJ, Jiang YB, Tian ZQ., Chem Soc Rev 43(1), 2014
PMID: 24061231
Three cobalt(II)-linked {P8W48} network assemblies: syntheses, structures, and magnetic and photocatalysis properties.
Jiao YQ, Qin C, Wang XL, Wang CG, Sun CY, Wang HN, Shao KZ, Su ZM., Chem Asian J 9(2), 2014
PMID: 24259485
Discovery of gigantic molecular nanostructures using a flow reaction array as a search engine.
Zang HY, de la Oliva AR, Miras HN, Long DL, McBurney RT, Cronin L., Nat Commun 5(), 2014
PMID: 24770632
Polyoxometalate based open-frameworks (POM-OFs).
Miras HN, Vilà-Nadal L, Cronin L., Chem Soc Rev 43(16), 2014
PMID: 25005364
Trimethyl and carboxymethyl chitosan carriers for bio-active polymer-inorganic nanocomposites.
Geisberger G, Gyenge EB, Maake C, Patzke GR., Carbohydr Polym 91(1), 2013
PMID: 23044105
Trimethyl and carboxymethyl chitosan carriers for bio-active polymer–inorganic nanocomposites
Geisberger G, Caroline Maake, Emina Besic Gyenge, Greta R. Patzke., Carbohydrate polymers. 91(1), 2013
PMID: IND600879982
Synthesis, characterization and bioimaging of fluorescent labeled polyoxometalates.
Geisberger G, Gyenge EB, Hinger D, Bösiger P, Maake C, Patzke GR., Dalton Trans 42(27), 2013
PMID: 23695527
{Mo24Fe12} macrocycles: anion templation with large polyoxometalate guests.
Fang X, Hansen L, Haso F, Yin P, Pandey A, Engelhardt L, Slowing I, Li T, Liu T, Luban M, Johnston DC., Angew Chem Int Ed Engl 52(40), 2013
PMID: 23943611
Assembly of thiometalate-based {Mo16 } and {Mo36 } composite clusters combining [Mo2O2S2 ](2+) cations and selenite anions.
Zang HY, Chen JJ, Chen JJ, Long DL, Cronin L, Miras HN., Adv Mater 25(43), 2013
PMID: 23970435
An unstable paramagnetic isopolyoxomolybdate intermediate non-homogeneously reduced at different sites and trapped in a host based on chemical adaptability.
Merca A, Garai S, Bögge H, Haupt ET, Ghosh A, López X, Poblet JM, Averseng F, Che M, Müller A., Angew Chem Int Ed Engl 52(45), 2013
PMID: 24108525
A redox-triggered structural rearrangement in an iodate-templated polyoxotungstate cluster cage.
Long DL, Yan J, Ruiz de la Oliva A, Busche C, Miras HN, Errington RJ, Cronin L., Chem Commun (Camb) 49(84), 2013
PMID: 24022579
Ionothermal synthesis of polyoxometalates.
Ahmed E, Ruck M., Angew Chem Int Ed Engl 51(2), 2012
PMID: 22121101
Three-dimensional ordered arrays of 58×58×58 Å3 hollow frameworks in ionic crystals of M2Zn2-substituted polyoxometalates.
Suzuki K, Kikukawa Y, Uchida S, Tokoro H, Imoto K, Ohkoshi S, Mizuno N., Angew Chem Int Ed Engl 51(7), 2012
PMID: 22234783
High-precision imaging of an encapsulated Lindqvist ion and correlation of its structure and symmetry with quantum chemical calculations.
Bichoutskaia E, Liu Z, Kuganathan N, Faulques E, Suenaga K, Shannon IJ, Sloan J., Nanoscale 4(4), 2012
PMID: 22252225
Cation induced structural transformation and mass spectrometric observation of the missing dodecavanadomanganate(IV).
Li F, Long DL, Cameron JM, Miras HN, Pradeep CP, Xu L, Cronin L., Dalton Trans 41(33), 2012
PMID: 22592605
Two Vernier-templated routes to a 24-porphyrin nanoring.
Kondratuk DV, Perdigao LM, O'Sullivan MC, Svatek S, Smith G, O'Shea JN, Beton PH, Anderson HL., Angew Chem Int Ed Engl 51(27), 2012
PMID: 22653879
Inorganic crown ethers: sulfate-based Preyssler polyoxometalates.
Zhang ZM, Yao S, Li YG, Han XB, Su ZM, Wang ZS, Wang EB., Chemistry 18(30), 2012
PMID: 22736581
Correlating the magic numbers of inorganic nanomolecular assemblies with a {Pd84} molecular-ring Rosetta Stone.
Xu F, Miras HN, Scullion RA, Long DL, Thiel J, Cronin L., Proc Natl Acad Sci U S A 109(29), 2012
PMID: 22753516
Engineering polyoxometalates with emergent properties.
Miras HN, Yan J, Long DL, Cronin L., Chem Soc Rev 41(22), 2012
PMID: 22858601
Configurable 3D-Printed millifluidic and microfluidic 'lab on a chip' reactionware devices.
Kitson PJ, Rosnes MH, Sans V, Dragone V, Cronin L., Lab Chip 12(18), 2012
PMID: 22875258
Polyoxometalate water oxidation catalysts and the production of green fuel.
Lv H, Geletii YV, Zhao C, Vickers JW, Zhu G, Luo Z, Song J, Lian T, Musaev DG, Hill CL., Chem Soc Rev 41(22), 2012
PMID: 22972187
Controlling the self-assembly of a mixed-metal Mo/V-selenite family of polyoxometalates.
Corella-Ochoa MN, Miras HN, Long DL, Cronin L., Chemistry 18(43), 2012
PMID: 22996730
A flow-system array for the discovery and scale up of inorganic clusters.
Richmond CJ, Miras HN, de la Oliva AR, Zang H, Sans V, Paramonov L, Makatsoris C, Inglis R, Brechin EK, Long DL, Cronin L., Nat Chem 4(12), 2012
PMID: 23174985
Directed assembly of inorganic polyoxometalate-based micrometer-scale tubular architectures by using optical control.
Cooper GJ, Bowman RW, Magennis EP, Fernandez-Trillo F, Alexander C, Padgett MJ, Cronin L., Angew Chem Int Ed Engl 51(51), 2012
PMID: 23161704
Assembly of a gigantic polyoxometalate cluster {W200Co8O660} in a networked reactor system.
de la Oliva AR, Sans V, Miras HN, Yan J, Zang H, Richmond CJ, Long DL, Cronin L., Angew Chem Int Ed Engl 51(51), 2012
PMID: 23180577
Chemical adaptability: the integration of different kinds of matter into giant molecular metal oxides.
Müller A, Merca A, Al-Karawi AJ, Garai S, Bögge H, Hou G, Wu L, Haupt ET, Rehder D, Haso F, Liu T., Chemistry 18(51), 2012
PMID: 23180718
Synthesis, characterisation and cytotoxicity of polyoxometalate/carboxymethyl chitosan nanocomposites.
Geisberger G, Paulus S, Carraro M, Bonchio M, Patzke GR., Chemistry 17(16), 2011
PMID: 21322072
Re-entrant phase behavior for systems with competition between phase separation and self-assembly.
Reinhardt A, Williamson AJ, Doye JP, Carrete J, Varela LM, Louis AA., J Chem Phys 134(10), 2011
PMID: 21405191
Polyoxometalate nanocone nanoreactors: magnetic manipulation and enhanced catalytic performance.
Nisar A, Lu Y, Zhuang J, Wang X., Angew Chem Int Ed Engl 50(14), 2011
PMID: 21370361
Hexagonal wheel formation through the hydrogen-bonded assembly of cobalt Pacman complexes.
Leeland JW, White FJ, Love JB., Chem Commun (Camb) 47(14), 2011
PMID: 21380429
Real-time observation of the self-assembly of hybrid polyoxometalates using mass spectrometry.
Wilson EF, Miras HN, Rosnes MH, Cronin L., Angew Chem Int Ed Engl 50(16), 2011
PMID: 21438104
Molecular growth of a core-shell polyoxometalate.
Fang X, Kögerler P, Furukawa Y, Speldrich M, Luban M., Angew Chem Int Ed Engl 50(22), 2011
PMID: 21506214
Reduced molybenum-oxide-based core-shell hybrids: "blue" electrons are delocalized on the shell.
Todea AM, Szakács J, Konar S, Bögge H, Crans DC, Glaser T, Rousselière H, Thouvenot R, Gouzerh P, Müller A., Chemistry 17(24), 2011
PMID: 21542032
Polyoxoniobate chemistry in the 21st century.
Nyman M., Dalton Trans 40(32), 2011
PMID: 21670824
A nanosized molybdenum oxide wheel with a unique electronic-necklace structure: STM study with submolecular resolution.
Zhong D, Sousa FL, Müller A, Chi L, Fuchs H., Angew Chem Int Ed Engl 50(31), 2011
PMID: 21717545
Assembly of a family of mixed metal {Mo:V} polyoxometalates templated by TeO3(2-): {Mo12V12Te3}, {Mo12V12Te2} and {Mo17V8Te}.
Corella-Ochoa MN, Miras HN, Kidd A, Long DL, Cronin L., Chem Commun (Camb) 47(31), 2011
PMID: 21734990
Targeted delivery of polyoxometalate nanocomposites.
Geisberger G, Paulus S, Gyenge EB, Maake C, Patzke GR., Small 7(19), 2011
PMID: 21953786
Investigating cation binding in the polyoxometalate-super-crown [P8W48O184]40-.
Boyd T, Mitchell SG, Gabb D, Long DL, Cronin L., Chemistry 17(43), 2011
PMID: 21953635
Isolation of a stable lacunary Dawson-type polyoxomolybdate cluster.
Hashikawa A, Fujimoto M, Hayashi Y, Miyasaka H., Chem Commun (Camb) 47(45), 2011
PMID: 22012482
Chemistry. Molecular donuts and donut holes.
Whitmire KH., Science 327(5961), 2010
PMID: 20044561
Polyoxometalates: building blocks for functional nanoscale systems.
Long DL, Tsunashima R, Cronin L., Angew Chem Int Ed Engl 49(10), 2010
PMID: 20131346
Nanotubular non-covalent macrocycle within non-covalent macrocycle assembly: (MeOH)(12) encapsulated in a molecular clip cyclododecamer.
Cao LP, Meng XG, Ding JY, Chen YF, Gao M, Wu YD, Li YT, Wu AX, Isaacs L., Chem Commun (Camb) 46(25), 2010
PMID: 20485785
Controlling transformations in the assembly of polyoxometalate clusters: {Mo11V7}, {Mo17V8} and {Mo72V30}.
Miras HN, Ochoa MN, Long DL, Cronin L., Chem Commun (Camb) 46(43), 2010
PMID: 20936202

17 References

Daten bereitgestellt von Europe PubMed Central.

Fluorous nanodroplets structurally confined in an organopalladium sphere.
Sato S, Iida J, Suzuki K, Kawano M, Ozeki T, Fujita M., Science 313(5791), 2006
PMID: 16946067
White phosphorus is air-stable within a self-assembled tetrahedral capsule.
Mal P, Breiner B, Rissanen K, Nitschke JR., Science 324(5935), 2009
PMID: 19556504
A route to high surface area, porosity and inclusion of large molecules in crystals.
Chae HK, Siberio-Perez DY, Kim J, Go Y, Eddaoudi M, Matzger AJ, O'Keeffe M, Yaghi OM., Nature 427(6974), 2004
PMID: 14765190
Highly controlled acetylene accommodation in a metal-organic microporous material.
Matsuda R, Kitaura R, Kitagawa S, Kubota Y, Belosludov RV, Kobayashi TC, Sakamoto H, Chiba T, Takata M, Kawazoe Y, Mita Y., Nature 436(7048), 2005
PMID: 16015325
Strategies for the Construction of Supramolecular Compounds through Coordination Chemistry.
Holliday BJ, Mirkin CA., Angew. Chem. Int. Ed. Engl. 40(11), 2001
PMID: 11433436
A molecular elevator.
Badjic JD, Balzani V, Credi A, Silvi S, Stoddart JF., Science 303(5665), 2004
PMID: 15031499

AUTHOR UNKNOWN, Nature 356(), 1992

AUTHOR UNKNOWN, Angew. Chem. Int. Ed. Engl. 34(), 1995

AUTHOR UNKNOWN, Coord Chem Rev 245(), 2003

AUTHOR UNKNOWN, Chem Soc Rev 36(), 2007
Soluble molybdenum blues-"des Pudels Kern".
Muller A, Serain C., Acc. Chem. Res. 33(1), 2000
PMID: 10639070

AUTHOR UNKNOWN, CHEM. EUR. J. 5(), 1999

AUTHOR UNKNOWN, PROG NMR SPECTROSCOPY 625(), 1999

AUTHOR UNKNOWN, Angew. Chem. Int. Ed. Engl. 36(), 1997

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