Metallization of organic monolayers: electroless deposition of Cu onto cross-linked aromatic self-assembled monolayers

Nottbohm CT, Turchanin A, Gölzhäuser A (2008)
In: ZEITSCHRIFT FÜR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS. 222. OLDENBOURG VERLAG: 917-926.

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We demonstrate the metallization of amino-terminated. cross-linked biphenylthiol self-assembled monolayers (SAMs) via Pd catalysed electroless deposition (ELD) of Cu. Angle resolved X-ray, photoelectron spectroscopy and atomic force microscopy were used for characterization. Lateral cross-linking and generation of terminal amino groups are induced by irradiation with low energy electrons. The cross-linked SAM Suppresses the ELD of Cu onto the Au substrate. By the immobilization of Pd atoms to the terminal amino groups, catalytic sites are created in cross-linked areas. These sites then facilitate the electroless deposition of Cu on top of the SAM.
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Nottbohm CT, Turchanin A, Gölzhäuser A. Metallization of organic monolayers: electroless deposition of Cu onto cross-linked aromatic self-assembled monolayers. In: ZEITSCHRIFT FÜR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS. Vol 222. OLDENBOURG VERLAG; 2008: 917-926.
Nottbohm, C. T., Turchanin, A., & Gölzhäuser, A. (2008). Metallization of organic monolayers: electroless deposition of Cu onto cross-linked aromatic self-assembled monolayers. ZEITSCHRIFT FÜR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, 222(5-6), 917-926.
Nottbohm, C. T., Turchanin, A., and Gölzhäuser, A. (2008). “Metallization of organic monolayers: electroless deposition of Cu onto cross-linked aromatic self-assembled monolayers” in ZEITSCHRIFT FÜR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, vol. 222, (OLDENBOURG VERLAG), 917-926.
Nottbohm, C.T., Turchanin, A., & Gölzhäuser, A., 2008. Metallization of organic monolayers: electroless deposition of Cu onto cross-linked aromatic self-assembled monolayers. In ZEITSCHRIFT FÜR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS. no.222 OLDENBOURG VERLAG, pp. 917-926.
C.T. Nottbohm, A. Turchanin, and A. Gölzhäuser, “Metallization of organic monolayers: electroless deposition of Cu onto cross-linked aromatic self-assembled monolayers”, ZEITSCHRIFT FÜR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, vol. 222, OLDENBOURG VERLAG, 2008, pp.917-926.
Nottbohm, C.T., Turchanin, A., Gölzhäuser, A.: Metallization of organic monolayers: electroless deposition of Cu onto cross-linked aromatic self-assembled monolayers. ZEITSCHRIFT FÜR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS. 222, p. 917-926. OLDENBOURG VERLAG (2008).
Nottbohm, Christoph T., Turchanin, Andrey, and Gölzhäuser, Armin. “Metallization of organic monolayers: electroless deposition of Cu onto cross-linked aromatic self-assembled monolayers”. ZEITSCHRIFT FÜR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS. OLDENBOURG VERLAG, 2008.Vol. 222. 917-926.
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