On the presence or absence of geminal Si ... N interactions (alpha-effect) in pentafluorophenylsilyl compounds with SiCN, SiNN and SiON backbones

Woski M, Berger R, Mitzel NW (2008)
DALTON TRANSACTIONS (41): 5652-5658.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
Abstract / Bemerkung
The silanes C6F5SiF2CH2NMe2 (1), C6F5SiF2N(SiMe3)NMe2 (2) and C6F5SiF2ONMe2 (3) with pentafluorophenyl substituents and geminal N atoms have been prepared by the reaction of C6F5SiF3 with LiCH2NMe2, LiN(SiMe3) NMe2 and LiONMe2, respectively. The compounds have been characterised by spectroscopic methods and crystal structure determination. Comparison of measured and calculated IR spectra has provided insight into the conformational composition of the vapour of 3. Whereas 2 and 3 show interactions between the geminal Si and N atoms, 1 does not. Further analysis of the bonding situation has been undertaken by quantum chemical calculations of the rotation and bending potentials of the C6F5SiF2-X-NMe2 units.
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DALTON TRANSACTIONS
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41
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5652-5658
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Woski M, Berger R, Mitzel NW. On the presence or absence of geminal Si .. N interactions (alpha-effect) in pentafluorophenylsilyl compounds with SiCN, SiNN and SiON backbones. DALTON TRANSACTIONS. 2008;(41):5652-5658.
Woski, M., Berger, R., & Mitzel, N. W. (2008). On the presence or absence of geminal Si .. N interactions (alpha-effect) in pentafluorophenylsilyl compounds with SiCN, SiNN and SiON backbones. DALTON TRANSACTIONS(41), 5652-5658. doi:10.1039/b808388f
Woski, M., Berger, R., and Mitzel, N. W. (2008). On the presence or absence of geminal Si .. N interactions (alpha-effect) in pentafluorophenylsilyl compounds with SiCN, SiNN and SiON backbones. DALTON TRANSACTIONS, 5652-5658.
Woski, M., Berger, R., & Mitzel, N.W., 2008. On the presence or absence of geminal Si .. N interactions (alpha-effect) in pentafluorophenylsilyl compounds with SiCN, SiNN and SiON backbones. DALTON TRANSACTIONS, (41), p 5652-5658.
M. Woski, R. Berger, and N.W. Mitzel, “On the presence or absence of geminal Si .. N interactions (alpha-effect) in pentafluorophenylsilyl compounds with SiCN, SiNN and SiON backbones”, DALTON TRANSACTIONS, 2008, pp. 5652-5658.
Woski, M., Berger, R., Mitzel, N.W.: On the presence or absence of geminal Si .. N interactions (alpha-effect) in pentafluorophenylsilyl compounds with SiCN, SiNN and SiON backbones. DALTON TRANSACTIONS. 5652-5658 (2008).
Woski, Markus, Berger, Raphael, and Mitzel, Norbert W. “On the presence or absence of geminal Si .. N interactions (alpha-effect) in pentafluorophenylsilyl compounds with SiCN, SiNN and SiON backbones”. DALTON TRANSACTIONS 41 (2008): 5652-5658.

3 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

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PMID: 26132269
Structural variations and molecular dynamics of rare-earth metal complexes with the N,N-bis(2-{pyrid-2-yl}ethyl)hydroxylaminato ligand.
Hellmann BJ, Venugopal A, Mix A, Neumann B, Stammler HG, Willner A, Pape T, Hepp A, Mitzel NW., Chemistry 15(43), 2009
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39 References

Daten bereitgestellt von Europe PubMed Central.


Kostyanovskii, Dokl. Akad. Nauk SSSR 164(), 1965

Kharpov, Zh. Obshch. Khim. 37(), 1967

Randall, Inorg. Chem. 6(), 1967

Pacl, Collect. Czech. Chem. Commun. 36(), 1971

Marchand, J. Organomet. Chem. 17(), 1969

Mital, J. Am. Chem. Soc. 91(), 1969

Bellama, J. Organomet. Chem. 24(), 1970

Egorochkin, Zh. Obshch. Khim. 46(), 1976

Musker, J. Organomet. Chem. 6(), 1966

Freeburger, J. Am. Chem. Soc. 93(), 1971

Ward, J. Inorg. Nucl. Chem. 20(), 1961

Lazareva, J. Chem. Soc., Perkin Trans. 2 (), 2002

Lazareva, Russ. Chem. Bull. 104(), 1995

Labreque, Organometallics 13(), 1994

Schindler, Adhaes.–Kleben Dichten 48(), 2004

Mitzel, J. Am. Chem. Soc. 119(), 1997

Mitzel, Angew. Chem. 109(), 1997

Losehand, Inorg. Chem. 37(), 1998

Mitzel, Eur. J. Inorg. Chem. (), 1998

Mitzel, Inorg. Chem. 38(), 1999

Mitzel, J. Chem. Soc., Dalton Trans. (), 1999
SiONB unit as reference for blocked Si...N interactions in SiON compounds.
Mitzel NW, Losehand U, Bauer B., Inorg Chem 39(9), 2000
PMID: 11428121

Losehand, J. Chem. Soc., Dalton Trans. (), 2000
Synthesis, decomposition, and structural studies in the gas phase and solid state of N,N-dimethylaminoxygermane.
Mitzel NW, Losehand U, Hinchley SL, Rankin DW., Inorg Chem 40(4), 2001
PMID: 11225108

Mitzel, Z. Naturforsch., B: Chem. Sci. 56(), 2001

Mitzel, J. Chem. Soc., Dalton Trans. (), 2002

Vojinović, Z. Naturforsch., B: Chem. Sci. 59(), 2004

Losehand, J. Chem. Soc., Dalton Trans. (), 1998
Synthesis of Volatile Cyclic Silylamines and the Molecular Structures of Two 1-Aza-2,5-disilacyclopentane Derivatives.
Mitzel NW, Schmidbaur H, Rankin DW, Smart BA, Hofmann M, Schleyer PR., Inorg Chem 36(20), 1997
PMID: 11670093

Mitzel, Chem.–Eur. J. 4(), 1998

Mitzel, J. Am. Chem. Soc. 120(), 1998

Mitzel, J. Am. Chem. Soc. 112(), 2000
Three-membered ring or open chain molecule - (F3C)F2SiONMe2 a model for the alpha-effect in silicon chemistry.
Mitzel NW, Vojinovic K, Frohlich R, Foerster T, Robertson HE, Borisenko KB, Rankin DW., J. Am. Chem. Soc. 127(39), 2005
PMID: 16190736

Vojinović, Chem.–Eur. J. 10(), 2004

Mitzel, Chem.–Eur. J. 11(), 2005

Mitzel, Organometallics 18(), 1999

Tacke, Organometallics 15(), 1996

Wannagat, Monatsh. Chem. 97(), 1966

Sheldrick, Acta Crystallogr., Sect. A: Found. Crystallogr. 46(), 1990

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